The Stephan Livera Podcast

Stephan Livera does a phenomenal job of interviewing highly technical subject matter experts, and explaining very complicated concepts in a way that is accessible to even non-technical listeners.

Bitcoin Fundamentals

The Bitcoin Fundamentals series is a great set of interviews of some of the most influential thought leaders in the Bitcoin space. There's a ton of great content here, and Preston Pysh is always an entertaining host.